Graphene/PbTe/n-Si Heterojunction Photodetector with Quasi-Type-Ι Band Alignment Enables a Broadband and Bias-Tunable Photoresponse
High-performance broadband photodetectors traditionally based on III-V and II-VI semiconductors, despite their commercial success in the near- and mid-infrared regions, suffer from high fabrication cost, poor CMOS compatibility, and the need for cryogenic cooling, thus limiting their large-scale integration. Here, we demonstrate a virtual graphene/PbTe/Si heterojunction photodetector fabricated by magnetron sputtering, offering a scalable and cost-effective route to high-performance optoelectronic devices. The device exhibits a bias-tunable photoresponse governed by quantum tunneling at the PbTe/Si interface. At ±3 V biases, the photocurrent differs by nearly 2 orders of magnitude under low light intensities, whereas a symmetric response with less than 5% variation is observed at high light intensities. Exploiting this nonlinear response, we establish a dual-mode optical communication scheme, where plaintext is transmitted at high intensities and encrypted inverse codes are generated under low intensities. This built-in encoding functionality enables a simple yet effective strategy for secure optical communication without complex external circuits. Moreover, the CMOS-compatible fabrication process ensures seamless integration with existing silicon photonic platforms, highlighting the potential of this approach for future large-scale on-chip optical communication technologies.
Authors
- Hongxi Zhou (ORCID: https://orcid.org/0000-0002-0721-5675)
- Chao Chen (ORCID: https://orcid.org/0000-0001-9106-0479)
- Guomin Mao
- Hang Yu (ORCID: https://orcid.org/0000-0003-2050-7346)
- Jiangchao Han (ORCID: https://orcid.org/0000-0002-5343-3091)
- Boo Hyun An (ORCID: https://orcid.org/0000-0002-1927-2474)
- Yunlu Lian
- Jun Gou (ORCID: https://orcid.org/0009-0004-8422-1421)
- Lixin Liu (ORCID: https://orcid.org/0000-0002-6550-5726)
- Jun Wang (ORCID: https://orcid.org/0000-0003-1699-3687)
- He Yu (ORCID: https://orcid.org/0000-0002-4639-1321)
- Yadong Jiang (ORCID: https://orcid.org/0000-0002-2777-8758)
- Jiamin Jiang (ORCID: https://orcid.org/0000-0001-6430-0676)
- Jinling Xie
- Han Dou
- Lei Guo (ORCID: https://orcid.org/0000-0002-0504-9132)
Institutions
- University of Electronic Science and Technology of China (CN)
- National Engineering Research Center of Electromagnetic Radiation Control Materials (CN)
- Detector Technology (United States) (US)
- State Key Laboratory of Electronic Thin Films and Integrated Devices
- Luoyang Institute of Science and Technology (CN)
Publication Details
- Journal
- ACS Applied Materials & Interfaces
- Published
- 2025-10-03
- DOI
- https://doi.org/10.1021/acsami.5c15473
- Primary Topic
- Photonic and Optical Devices
- Type
- article
- Field-Weighted Citation Impact
- 0.00