Modeling Magnetic Transition Temperature of Rare-Earth Transition Metal-Based Double Perovskite Ceramics for Cryogenic Refrigeration Applications Using Intelligent Computational Methods

Rare-earth transition metal-based double perovskite ceramics E<sub>2</sub>TMO<sub>6</sub> (where E = rare-earth metals, T = transition metals, and M = metal) have received impressive attention lately for cryogenic applications as a result of their intrinsic physical features such as multiferroicity, dielectric features, and adjustable magnetic transition temperature. However, determination and enhancement of magnetic transition temperature of E<sub>2</sub>TMO<sub>6</sub> ceramic are subject to experimental procedures and processes with a significant degree of difficulties and cumbersomeness. This work proposes an extreme learning machine (ELM)-based intelligent method of determining magnetic transition temperature of E<sub>2</sub>TMO<sub>6</sub> ceramics with activation function sigmoid (SM) and sine (SE) at varying magnetic field. The outcomes of the SE-ELM and SM-ELM models were compared with genetically optimized support vector regression (GEN-SVR) predictive models using RMSE, CC, and MAE metrics. Using the testing samples of E<sub>2</sub>TMO<sub>6</sub> ceramics, SE-ELM predictive model outperforms GEN-SVR with a superiority of 6.3% (using RMSE metric) and 15.7% (using MAE metric). The SE-ELM predictive model further outperforms the SM-ELM model, with an improvement of 5.3%, using CC computed with training ceramic samples. The simplicity of the employed descriptors, coupled with the outstanding performance of the developed predictive models, would potentially strengthen E<sub>2</sub>TMO<sub>6</sub> ceramics exploration for low-temperature cryogenic applications and circumvent energy challenges in different sectors.

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Publication Details

Journal
Materials
Published
2025-10-03
DOI
https://doi.org/10.3390/ma18194594
Primary Topic
Advanced Thermoelectric Materials and Devices
Type
article
Field-Weighted Citation Impact
0.00

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article

Modeling Magnetic Transition Temperature of Rare-Earth Transition Metal-Based Double Perovskite Ceramics for Cryogenic Refrigeration Applications Using Intelligent Computational Methods

Sami M. Ibn Shamsah
Materials
Advanced Thermoelectric Materials and Devices
article

Modeling Magnetic Transition Temperature of Rare-Earth Transition Metal-Based Double Perovskite Ceramics for Cryogenic Refrigeration Applications Using Intelligent Computational Methods

Sami M. Ibn Shamsah
article en

Abstract

Rare-earth transition metal-based double perovskite ceramics E<sub>2</sub>TMO<sub>6</sub> (where E = rare-earth metals, T = transition metals, and M = metal) have received impressive attention lately for cryogenic applications as a result of their intrinsic physical features such as multiferroicity, dielectric features, and adjustable magnetic transition temperature. However, determination and enhancement of magnetic transition temperature of E<sub>2</sub>TMO<sub>6</sub> ceramic are subject to experimental procedures and processes with a significant degree of difficulties and cumbersomeness. This work proposes an extreme learning machine (ELM)-based intelligent method of determining magnetic transition temperature of E<sub>2</sub>TMO<sub>6</sub> ceramics with activation function sigmoid (SM) and sine (SE) at varying magnetic field. The outcomes of the SE-ELM and SM-ELM models were compared with genetically optimized support vector regression (GEN-SVR) predictive models using RMSE, CC, and MAE metrics. Using the testing samples of E<sub>2</sub>TMO<sub>6</sub> ceramics, SE-ELM predictive model outperforms GEN-SVR with a superiority of 6.3% (using RMSE metric) and 15.7% (using MAE metric). The SE-ELM predictive model further outperforms the SM-ELM model, with an improvement of 5.3%, using CC computed with training ceramic samples. The simplicity of the employed descriptors, coupled with the outstanding performance of the developed predictive models, would potentially strengthen E<sub>2</sub>TMO<sub>6</sub> ceramics exploration for low-temperature cryogenic applications and circumvent energy challenges in different sectors.

MaterialsVol. 18(19)
University of Hafr Al-Batin (SA)
University of Hafr Al Batin
Openalex Percentile: Top 79%
Advanced Thermoelectric Materials and Devices
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