Study on the Strength Characteristics of Ion-Adsorbed Rare Earth Ore Under Chemical Leaching and the Duncan–Chang Model Parameters
Ionic rare earths are extracted from primary sources by the in situ chemical leaching method, where the type and concentration of leaching agents significantly affect the mechanical properties and microstructure of the ore body. In this study, MgSO4 and Al2(SO4)3 solutions of varying concentrations were used as leaching agents to investigate the evolution of shear strength, the characteristics of Duncan–Chang hyperbolic model parameters, and the changes in microstructural pore characteristics of rare earth samples under different leaching conditions. The results show that the stress–strain curves of all samples consistently exhibit strain-hardening behavior under all leaching conditions, and shear strength is jointly influenced by confining pressure and the chemical interaction between the leaching solution and the soil. The samples leached with MgSO4 exhibited higher shear strength than those treated with water. The samples leached with 3% and 6% Al2(SO4)3 showed increased strength, while 9% Al2(SO4)3 caused a slight decrease. With increasing leaching agent concentration, the cohesion of the samples significantly declined, whereas the internal friction angle remained relatively stable. The Duncan–Chang model accurately described the nonlinear deformation behavior of the rare earth samples, with the model parameter b markedly decreasing as confining pressure increased, indicating that confining stress plays a dominant role in governing the nonlinear response. Under the coupled effects of chemical leaching and mechanical stress, the number and size distribution of pores of the rare earth samples underwent a complex multiscale co-evolution. These results provide theoretical support for the green, efficient, and safe exploitation of ionic rare earth ores.
Authors
- Zhongqun Guo (ORCID: https://orcid.org/0000-0002-6517-3258)
- Xiaoming Lin (ORCID: https://orcid.org/0000-0001-8835-103X)
- Qiqi Liu
- Haoxuan Wang (ORCID: https://orcid.org/0009-0003-8318-4529)
- Jianqi Wu
Institutions
- Ministry of Natural Resources (CN)
- Jiangxi University of Science and Technology (CN)
Publication Details
- Journal
- Metals
- Published
- 2025-10-03
- DOI
- https://doi.org/10.3390/met15101104
- Primary Topic
- Geochemistry and Elemental Analysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00