CONDITIONS FOR FORMATION OF STRUCTURE OF POROUS HYBRID MATERIALS FROM CELLULOSIC FABRIC AND MACROMOLECULAR -SUBSTITUTED CYCLIC AMINOACETATES WITH GRAFTED AEROSIL MICROPARTICLES

The stages of synthesis of porous hybrid material from cellulose fabric and macromolecular -substituted cyclic aminoacetates with grafted aerosil microparticles are studied. Such a structure is found to be formed if the cellulose fibers are filled with a suspension of agglomerates of aerosil particles in PVC shells, the diameter of which is greater than the width of the gaps between the microfibril ribbons. Ribbons and fibrils are cross-linked by grafting PVC macromolecules simultaneously to cellulose on the surface of the ends and to the surface of the aerosil particles. The frameworks are strengthened and the porous structure is formed as linear PVC macromolecules grafted to cellulose and to aerosil are transformed into cyclic amine structures.

Authors

Publication Details

Journal
Журнал физической химии / Russian Journal of Physical Chemistry
Published
2025-01-01
DOI
https://doi.org/10.7868/s3034553725050101
Primary Topic
biodegradable polymer synthesis and properties
Type
article
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article

CONDITIONS FOR FORMATION OF STRUCTURE OF POROUS HYBRID MATERIALS FROM CELLULOSIC FABRIC AND MACROMOLECULAR -SUBSTITUTED CYCLIC AMINOACETATES WITH GRAFTED AEROSIL MICROPARTICLES

M. R. Kobrin
Журнал физической химии / Russian Journal of Physical Chemistry
biodegradable polymer synthesis and properties
article

CONDITIONS FOR FORMATION OF STRUCTURE OF POROUS HYBRID MATERIALS FROM CELLULOSIC FABRIC AND MACROMOLECULAR -SUBSTITUTED CYCLIC AMINOACETATES WITH GRAFTED AEROSIL MICROPARTICLES

M. R. Kobrin
article en

Abstract

The stages of synthesis of porous hybrid material from cellulose fabric and macromolecular -substituted cyclic aminoacetates with grafted aerosil microparticles are studied. Such a structure is found to be formed if the cellulose fibers are filled with a suspension of agglomerates of aerosil particles in PVC shells, the diameter of which is greater than the width of the gaps between the microfibril ribbons. Ribbons and fibrils are cross-linked by grafting PVC macromolecules simultaneously to cellulose on the surface of the ends and to the surface of the aerosil particles. The frameworks are strengthened and the porous structure is formed as linear PVC macromolecules grafted to cellulose and to aerosil are transformed into cyclic amine structures.

Журнал физической химии / Russian Journal of Physical ChemistryVol. 99(5)
Openalex Percentile: Top 82%
biodegradable polymer synthesis and properties
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