Using chemical nuclear polarization effects to study photo-rearrangement of sulfur-containing thioesters

Fries photo-rearrangement of the thioester of para-methyl benzocarbothiol in a number of solvents is studied using CIDNP technique. It is shown that the reaction occurs with the formation of radical pairs in the singlet state. The elementary stages of the reaction are determined.

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Publication Details

Journal
Журнал физической химии / Russian Journal of Physical Chemistry
Published
2025-01-01
DOI
https://doi.org/10.7868/s3034553725030127
Primary Topic
Organic Chemistry Cycloaddition Reactions
Type
article
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article

Using chemical nuclear polarization effects to study photo-rearrangement of sulfur-containing thioesters

В. И. Порхун
Журнал физической химии / Russian Journal of Physical Chemistry
Organic Chemistry Cycloaddition Reactions
article

Using chemical nuclear polarization effects to study photo-rearrangement of sulfur-containing thioesters

В. И. Порхун
article en

Abstract

Fries photo-rearrangement of the thioester of para-methyl benzocarbothiol in a number of solvents is studied using CIDNP technique. It is shown that the reaction occurs with the formation of radical pairs in the singlet state. The elementary stages of the reaction are determined.

Журнал физической химии / Russian Journal of Physical ChemistryVol. 99(3)
Openalex Percentile: Top 79%
Organic Chemistry Cycloaddition Reactions
DOISourceOpenAlex
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Using chemical nuclear polarization effects to study photo-rearrangement of sulfur-containing thioesters — В. И. Порхун · Журнал физической химии / Russian Journal of Physical Chemistry (2025) | TGRS Research Map | TGRS