SORPTION-DESCRIPTION PROPERTIES OF TITANIUM PHOSPHATE TOWARDS HEAVY METALS CATIONS

The sorption/desorption behavior of divalent ions (, , , ) on amorphous titanium phosphate is studied. The sorption/desorption equilibrium is shown to be largely determined by the solvated state of heavy metal cations; selectivity series are constructed. Regardless of the degree of saturation of the sorbent with cations of the metals being studied, the desorption degree exceeds 99.9% in all cases. With multi-stage use of the sorbent, the efficiency of sorption/desorption processes is established to decrease because of its dehydration due to hydrolysis of the sorbent, which is 2.6×10 mg·g·h. The efficiency of sorption/desorption of the ions from multicomponent solutions is shown.

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Publication Details

Journal
Журнал физической химии / Russian Journal of Physical Chemistry
Published
2025-01-01
DOI
https://doi.org/10.7868/s3034553725050098
Primary Topic
Chemical Synthesis and Characterization
Type
article
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article

SORPTION-DESCRIPTION PROPERTIES OF TITANIUM PHOSPHATE TOWARDS HEAVY METALS CATIONS

Maria V. Maslova
Журнал физической химии / Russian Journal of Physical Chemistry
Chemical Synthesis and Characterization
article

SORPTION-DESCRIPTION PROPERTIES OF TITANIUM PHOSPHATE TOWARDS HEAVY METALS CATIONS

Maria V. Maslova
article en

Abstract

The sorption/desorption behavior of divalent ions (, , , ) on amorphous titanium phosphate is studied. The sorption/desorption equilibrium is shown to be largely determined by the solvated state of heavy metal cations; selectivity series are constructed. Regardless of the degree of saturation of the sorbent with cations of the metals being studied, the desorption degree exceeds 99.9% in all cases. With multi-stage use of the sorbent, the efficiency of sorption/desorption processes is established to decrease because of its dehydration due to hydrolysis of the sorbent, which is 2.6×10 mg·g·h. The efficiency of sorption/desorption of the ions from multicomponent solutions is shown.

Журнал физической химии / Russian Journal of Physical ChemistryVol. 99(5)
Openalex Percentile: Top 67%
Chemical Synthesis and Characterization
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