Synthesis and structure of water-soluble complexes of copper fumarate and succinate with monoethanolamine

New water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50°C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc) · 2MEA] · H2O and [Cu(Fum) · 2MEA] · H2O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.

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Publication Details

Journal
Координационная химия / Russian Journal of Coordination Chemistry
Published
2025-01-01
DOI
https://doi.org/10.7868/s3034549925020032
Primary Topic
Inorganic and Organometallic Chemistry
Type
article
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article

Synthesis and structure of water-soluble complexes of copper fumarate and succinate with monoethanolamine

Б. И. Петров
Координационная химия / Russian Journal of Coordination Chemistry
Inorganic and Organometallic Chemistry
article

Synthesis and structure of water-soluble complexes of copper fumarate and succinate with monoethanolamine

Б. И. Петров
article en

Abstract

New water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50°C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc) · 2MEA] · H2O and [Cu(Fum) · 2MEA] · H2O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.

Координационная химия / Russian Journal of Coordination ChemistryVol. 51(2)
Openalex Percentile: Top 79%
Inorganic and Organometallic Chemistry
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