Pore-confined trimerization of terephthalonitrile in MAF-5
The nitrile trimerization reaction of terephthalonitrile requires catalysts and a temperature above 400 °C, and yields polymers. When confined in a metal-organic framework, MAF-5, the reaction temperature lowers to 240 °C without using catalysts, and the product becomes a unitary trimer.
Authors
- Luhua Jiang (ORCID: https://orcid.org/0000-0002-1462-3693)
- Hao‐Long Zhou (ORCID: https://orcid.org/0000-0002-5007-6535)
- Xiao‐Chun Huang (ORCID: https://orcid.org/0000-0001-5495-7914)
- Rui‐Biao Lin
- Xiong‐Hai Chen
- Dong‐Dong Zhou (ORCID: https://orcid.org/0000-0003-1105-8702)
- Jie‐Peng Zhang (ORCID: https://orcid.org/0000-0002-2614-2774)
- Xing-Tian Qiu
- Xuewen Zhang (ORCID: https://orcid.org/0000-0001-7373-3764)
Institutions
- Sun Yat-sen University (CN)
- Shantou University (CN)
- Ji Hua Laboratory (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04880j
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00