A 3D cobalt corrole-based Zr-MOF for the selective adsorption of carbon monoxide
Two 3D MOFs based on triphenylcorrole and its cobalt-metalated analog (CoCorr-MOF) are presented. They show a hexagonal structure, a homogeneous particle size, and microporosity with a specific area of 390 and 304 m<sup>2</sup> g<sup>-1</sup>, respectively. The CoCorr-MOF presents a better affinity for CO than for other interferents (N<sub>2</sub>, CO<sub>2</sub> and O<sub>2</sub>), demonstrating a CO chemisorption capacity of 7.2 cm<sup>3</sup> g<sup>-1</sup> with high selectivity.
Authors
- Laurie André (ORCID: https://orcid.org/0000-0002-9574-9617)
- Nicolas Desbois (ORCID: https://orcid.org/0000-0002-1156-4608)
- Claude P. Gros (ORCID: https://orcid.org/0000-0002-6966-947X)
- Stéphane Brandès (ORCID: https://orcid.org/0000-0001-6923-1630)
- Jian Yang (ORCID: https://orcid.org/0000-0003-0412-5831)
- Ken Rapady
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Bourgogne (FR)
- Université Bourgogne Europe (FR)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04145g
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00