Standard thermodynamic properties of Ag<sub>3</sub>Sn (shosanbetsuite): EMF data

Thermodynamic properties of shosanbetsuite (Ag3Sn) are first determined in the Ag–Sn system in a galvanic cell (–) Pt | Gr | Ag | RbAg4I5 | Ag3Sn, Sn | Gr | Pt (+) within the temperature range of 327–427 K in vacuum. Analysis of the data makes it possible to calculate the standard (298.15 K, 105 Pa) ΔfG0, ΔfH0, and S0 of Ag3Sn: –21238, –18763 J mol–1, and 187.5 J K–1 mol–1, respectively.

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Publication Details

Journal
Геохимия / Geochemistry International
Published
2025-01-01
DOI
https://doi.org/10.7868/s3034495625020042
Primary Topic
Thermal and Kinetic Analysis
Type
article
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article

Standard thermodynamic properties of Ag<sub>3</sub>Sn (shosanbetsuite): EMF data

M. I. Voronin
Геохимия / Geochemistry International
Thermal and Kinetic Analysis
article

Standard thermodynamic properties of Ag<sub>3</sub>Sn (shosanbetsuite): EMF data

M. I. Voronin
article en

Abstract

Thermodynamic properties of shosanbetsuite (Ag3Sn) are first determined in the Ag–Sn system in a galvanic cell (–) Pt | Gr | Ag | RbAg4I5 | Ag3Sn, Sn | Gr | Pt (+) within the temperature range of 327–427 K in vacuum. Analysis of the data makes it possible to calculate the standard (298.15 K, 105 Pa) ΔfG0, ΔfH0, and S0 of Ag3Sn: –21238, –18763 J mol–1, and 187.5 J K–1 mol–1, respectively.

Геохимия / Geochemistry InternationalVol. 70(2)
Openalex Percentile: Top 79%
Thermal and Kinetic Analysis
DOISourceOpenAlex
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Standard thermodynamic properties of Ag<sub>3</sub>Sn (shosanbetsuite): EMF data — M. I. Voronin · Геохимия / Geochemistry International (2025) | TGRS Research Map | TGRS