Unraveling steric and dispersion effects in gold catalysis: a DFT study of asymmetric cyclization/Mannich reactions
Gold and chiral phosphoric acid cooperatively catalyze the asymmetric oxidative cyclization/Mannich reaction of homopropargyl amides to efficiently access enantioenriched spiroindolenines.
Authors
- Rui Jin (ORCID: https://orcid.org/0000-0002-7946-3686)
- Jin Qian (ORCID: https://orcid.org/0000-0002-9368-387X)
- Ruiyu Liu (ORCID: https://orcid.org/0000-0002-2006-0655)
- Ke Chu (ORCID: https://orcid.org/0000-0002-0606-2689)
- Yunhe Li (ORCID: https://orcid.org/0000-0002-5386-6727)
Institutions
- Lanzhou Jiaotong University (CN)
- Xi'an Jiaotong University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo01230a
- Primary Topic
- Catalytic Processes in Materials Science
- Type
- article
- Field-Weighted Citation Impact
- 0.00