β-Carboxyphospholes <i>via</i> carboxylative desilylation: luminophores with a versatile connectivity attached
The synthesis of β-carboxyphospholes has been achieved <i>via</i> carboxylative desilylation of their β-TMS-substituted analogues in a CO<sub>2</sub> atmosphere. The title carboxylic acids allow facile transformation into the respective acyl chloride, carboxamide, ester and anhydride, which are compatible with bioconjugation, while the integrity of the phosphole unit is maintained.
Authors
- Clemens Bruhn
- Rudolf Pietschnig (ORCID: https://orcid.org/0000-0003-0551-3633)
- K. Eichhorn
Institutions
- University of Kassel (DE)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04850h
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00