Stepwise selective crystallization of Fe and Dy complexes from a Fe/Nd/Dy mixture: separation despite charge and solubility similarity
Selective crystallization of charge-identical trenSal complexes enabled stepwise separation of Fe, Nd, and Dy. Remarkably, high selectivity emerged under controlled-base conditions, allowing separation even between species with similar solubilities. This study demonstrates a new approach for f/f and f/d metal separation based on controlled crystallization behavior.
Authors
- Hideyuki Masaki
- Atsuko Masuya‐Suzuki (ORCID: https://orcid.org/0000-0001-9392-3741)
- Natsuki Hasegawa (ORCID: https://orcid.org/0000-0002-5747-611X)
- Ryo Tsunashima (ORCID: https://orcid.org/0000-0002-8852-6992)
- Akira Kirishima
- Akiho Yanai
Institutions
- Yamaguchi University (JP)
- Tohoku University (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03074a
- Primary Topic
- Extraction and Separation Processes
- Type
- article
- Field-Weighted Citation Impact
- 0.00