Exact solution of asymmetric gelation between three walks on the square lattice

Abstract We find and analyse the exact solution of a model of three different polymers with asymmetric contact interactions in two dimensions, modelling a scenario where there are different types of polymers involved. In particular, we find the generating function of three directed osculating walks in star configurations on the square lattice with two interaction Boltzmann weights, so that there is one type of contact interaction between the top pair of walks and a different interaction between the bottom pair of walks. These osculating stars are found to be the most amenable to exact solution using functional equation techniques in comparison to the symmetric case where three friendly walks in watermelon configurations were successfully solved with the same techniques. We elucidate the phase diagram, which has four phases, and find the order of all the phase transitions between them. We also calculate the entropic exponents in each phase.

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Publication Details

Journal
Journal of Physics A Mathematical and Theoretical
Published
2025-09-30
DOI
https://doi.org/10.1088/1751-8121/ae0dcc
Primary Topic
Supramolecular Self-Assembly in Materials
Type
article
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article

Exact solution of asymmetric gelation between three walks on the square lattice

A L Owczarek, Andrew Rechnitzer
Journal of Physics A Mathematical and Theoretical
Supramolecular Self-Assembly in Materials
article

Exact solution of asymmetric gelation between three walks on the square lattice

A L Owczarek, Andrew Rechnitzer
article en

Abstract

Abstract We find and analyse the exact solution of a model of three different polymers with asymmetric contact interactions in two dimensions, modelling a scenario where there are different types of polymers involved. In particular, we find the generating function of three directed osculating walks in star configurations on the square lattice with two interaction Boltzmann weights, so that there is one type of contact interaction between the top pair of walks and a different interaction between the bottom pair of walks. These osculating stars are found to be the most amenable to exact solution using functional equation techniques in comparison to the symmetric case where three friendly walks in watermelon configurations were successfully solved with the same techniques. We elucidate the phase diagram, which has four phases, and find the order of all the phase transitions between them. We also calculate the entropic exponents in each phase.

Journal of Physics A Mathematical and TheoreticalVol. 58(42)
University of British Columbia (CA)
Openalex Percentile: Top 83%
Supramolecular Self-Assembly in Materials
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