Unifying dynamics of glass-forming liquids by crystallization temperature

A crucial question pertaining to the understanding of the elusive glass transition concerns the existence of a universal framework that can describe the dynamics of various glass-forming liquids. Here, we report our achievement of a comprehensive unification of dynamics via the utilization of the crystallization temperature. We provide evidence that the pressure-dependent crystallization temperature links numerous pivotal features of multiple glass-forming liquids, including the super-Arrhenius structural relaxation, dynamical heterogeneity, caging behavior, glass fragility, onset temperature and glass transition temperature. The significant role played by the crystallization temperature reveals the underlying connections between non-equilibrium glass formers and their equilibrium counterparts.

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Publication Details

Journal
National Science Review
Published
2025-09-29
DOI
https://doi.org/10.1093/nsr/nwaf423
Primary Topic
Material Science and Thermodynamics
Type
article
Field-Weighted Citation Impact
0.00

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article

Unifying dynamics of glass-forming liquids by crystallization temperature

Ning Xu, Yunhuan Nie, Huiming Cao, Pengfei Guan et al.
National Science Review
Material Science and Thermodynamics
article

Unifying dynamics of glass-forming liquids by crystallization temperature

Ning Xu, Yunhuan Nie, Huiming Cao, Pengfei Guan, Lijin Wang
article en

Abstract

A crucial question pertaining to the understanding of the elusive glass transition concerns the existence of a universal framework that can describe the dynamics of various glass-forming liquids. Here, we report our achievement of a comprehensive unification of dynamics via the utilization of the crystallization temperature. We provide evidence that the pressure-dependent crystallization temperature links numerous pivotal features of multiple glass-forming liquids, including the super-Arrhenius structural relaxation, dynamical heterogeneity, caging behavior, glass fragility, onset temperature and glass transition temperature. The significant role played by the crystallization temperature reveals the underlying connections between non-equilibrium glass formers and their equilibrium counterparts.

National Science ReviewVol. 12(12)
University of Science and Technology of China (CN), Anhui University (CN), Guizhou University (CN), Hefei National Center for Physical Sciences at Nanoscale (CN), Ningbo Institute of Industrial Technology (CN)
National Natural Science Foundation of China, China Postdoctoral Science Foundation, University of Science and Technology of China
Openalex Percentile: Top 72%
Material Science and Thermodynamics
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Unifying dynamics of glass-forming liquids by crystallization temperature — Ning Xu, Yunhuan Nie, et al. · National Science Review (2025) | TGRS Research Map | TGRS