Unifying dynamics of glass-forming liquids by crystallization temperature
A crucial question pertaining to the understanding of the elusive glass transition concerns the existence of a universal framework that can describe the dynamics of various glass-forming liquids. Here, we report our achievement of a comprehensive unification of dynamics via the utilization of the crystallization temperature. We provide evidence that the pressure-dependent crystallization temperature links numerous pivotal features of multiple glass-forming liquids, including the super-Arrhenius structural relaxation, dynamical heterogeneity, caging behavior, glass fragility, onset temperature and glass transition temperature. The significant role played by the crystallization temperature reveals the underlying connections between non-equilibrium glass formers and their equilibrium counterparts.
Authors
- Ning Xu (ORCID: https://orcid.org/0000-0002-1905-8558)
- Yunhuan Nie (ORCID: https://orcid.org/0000-0002-4385-4562)
- Huiming Cao (ORCID: https://orcid.org/0000-0002-6010-8895)
- Pengfei Guan (ORCID: https://orcid.org/0000-0001-8107-1852)
- Lijin Wang (ORCID: https://orcid.org/0000-0001-8229-4820)
Institutions
- University of Science and Technology of China (CN)
- Anhui University (CN)
- Guizhou University (CN)
- Hefei National Center for Physical Sciences at Nanoscale (CN)
- Ningbo Institute of Industrial Technology (CN)
Publication Details
- Journal
- National Science Review
- Published
- 2025-09-29
- DOI
- https://doi.org/10.1093/nsr/nwaf423
- Primary Topic
- Material Science and Thermodynamics
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- China Postdoctoral Science Foundation
- University of Science and Technology of China