Carbon black-filled polyurethane foam as a core for sandwich panels

This study presents the development and characterization of rigid polyurethane foams (RPUFs) reinforced with carbon black (CB) particles (0.5%, 1.0%, and 3.0% wt.), engineered as lightweight core materials for structural sandwich panels. The novelty lies in the use of CB as a cost-effective nanofiller to improve both mechanical and morphological properties of RPUFs while reducing density. The foams exhibited closed-cell, anisotropic structures, with the 0.5% and 1.0% CB formulations showing enhanced cell alignment and reduced cell size. Significant mechanical improvements were achieved: compressive strength increased by 41.7% and 45.8%, and compressive modulus by 33.3% and 9.5% for the 0.5% and 1.0% CB foams, respectively, compared to neat RPUF. These enhancements are attributed to effective filler–matrix interaction and optimized foam microstructure. In contrast, the 3.0% CB foam displayed poor dispersion, leading to structural defects and reduced mechanical performance. When applied as sandwich panel cores, the 0.5% CB formulation led to improvements of 54.5% in specific flexural stiffness and 37.5% in core shear strength. These results demonstrate that low CB contents can simultaneously reduce density and improve mechanical efficiency, highlighting their potential for use in lightweight, high-performance structural applications in automotive, construction, and insulation systems.

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Publication Details

Journal
Journal of Cellular Plastics
Published
2025-09-12
DOI
https://doi.org/10.1177/0021955x251379807
Primary Topic
Polymer composites and self-healing
Type
article
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article

Carbon black-filled polyurethane foam as a core for sandwich panels

André Luiz Missio, Andrey Pereira Acosta, Marlon Bender Bueno Rodrigues, Kelvin Techera Barbosa et al.
Journal of Cellular Plastics
Polymer composites and self-healing
article

Carbon black-filled polyurethane foam as a core for sandwich panels

André Luiz Missio, Andrey Pereira Acosta, Marlon Bender Bueno Rodrigues, Kelvin Techera Barbosa, Joziel Aparecido da Cruz, Rafael de Ávila Delucis, D. Ramos, Larissa Queiroz Minillo
article en

Abstract

This study presents the development and characterization of rigid polyurethane foams (RPUFs) reinforced with carbon black (CB) particles (0.5%, 1.0%, and 3.0% wt.), engineered as lightweight core materials for structural sandwich panels. The novelty lies in the use of CB as a cost-effective nanofiller to improve both mechanical and morphological properties of RPUFs while reducing density. The foams exhibited closed-cell, anisotropic structures, with the 0.5% and 1.0% CB formulations showing enhanced cell alignment and reduced cell size. Significant mechanical improvements were achieved: compressive strength increased by 41.7% and 45.8%, and compressive modulus by 33.3% and 9.5% for the 0.5% and 1.0% CB foams, respectively, compared to neat RPUF. These enhancements are attributed to effective filler–matrix interaction and optimized foam microstructure. In contrast, the 3.0% CB foam displayed poor dispersion, leading to structural defects and reduced mechanical performance. When applied as sandwich panel cores, the 0.5% CB formulation led to improvements of 54.5% in specific flexural stiffness and 37.5% in core shear strength. These results demonstrate that low CB contents can simultaneously reduce density and improve mechanical efficiency, highlighting their potential for use in lightweight, high-performance structural applications in automotive, construction, and insulation systems.

Journal of Cellular PlasticsVol. 62(1)
Universidade Federal do Rio Grande do Sul (BR), Universidade Federal de Pelotas (BR), Universidade Federal de Santa Catarina (BR), U-center (NL), Universidade Federal do Paraná (BR), University of Rio Grande and Rio Grande Community College (US)
Openalex Percentile: Top 77%
Polymer composites and self-healing
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