S-Triazin İçeren Çok Dişli Schiff Bazlarının Sentezi ve Karakterizasyonu: Bazı Geçiş Metali Komplekslerinin İncelenmesi

In this paper, two basic mid-products were obtained by reacting cyanuric chloride and hydroquinone or 1,4-phenylendiamine, respectively. EBA1 and EBA2 were obtained from the reaction of these compounds and 4-hydroxybenzaldehyde. Four target ligands encoded as EBL1-EBL4 were obtained by reacting these compounds with 4-aminobenzoic acid and 5-aminoisophthalic acid, respectively. These obtained ligands were characterized by FTIR, elemental analysis, 1H and 13C NMR and methods. The obtained target ligands were reacted with [M(Salen/Saloph)]2O (M= Cr3+ and Fe3+) to obtain [M(Salen/Saloph)] capped complexes. These complexes were characterized using elemental analysis, and FTIR. The magnetic properties of the complexes were investigated. The thermal endurance of the complexes was determined using the TGA technique. At the end of the study, 6 tetrapodal ligands and 16 tetrapodal complexes, which are thermally stable with paramagnetic properties, were synthesized and characterized.