Energy additivity as a requirement for universal quantum thermodynamical frameworks

The quest to develop a general framework for thermodynamics, suitable for the regime of strong coupling and correlations between subsystems of an autonomous quantum "universe," has entailed diverging definitions for basic quantities, including internal energy. While most approaches focus solely on the system of interest, we propose that a universal notion of internal energy should also account for the environment in order to keep consistency with the closed-system energy of the universe. We introduce an abstract framework to describe all effective Hamiltonian-based approaches and address a rigorous definition of energy additivity in this context, in both a weak and a strong form, discussing the underlying subtleties. As an illustration, we study a particular two-qubit universe model, obtaining the exact master equations for both parties and calculating their effective Hamiltonians and internal energies as given by the recently devised minimal dissipation approach. In this case, we show that internal energies are neither additive nor conservative, which leads to unphysical features.

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Publication Details

Journal
Scientific Reports
Published
2025-09-26
DOI
https://doi.org/10.1038/s41598-025-15833-9
Citations
2
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
2.65

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article

Energy additivity as a requirement for universal quantum thermodynamical frameworks

Frederico Brito, Luis Rodrigo Torres Neves
2 citations
Scientific Reports
Advanced Thermodynamics and Statistical Mechanics
2.65
article

Energy additivity as a requirement for universal quantum thermodynamical frameworks

Frederico Brito, Luis Rodrigo Torres Neves
article en
2 citations

Abstract

The quest to develop a general framework for thermodynamics, suitable for the regime of strong coupling and correlations between subsystems of an autonomous quantum "universe," has entailed diverging definitions for basic quantities, including internal energy. While most approaches focus solely on the system of interest, we propose that a universal notion of internal energy should also account for the environment in order to keep consistency with the closed-system energy of the universe. We introduce an abstract framework to describe all effective Hamiltonian-based approaches and address a rigorous definition of energy additivity in this context, in both a weak and a strong form, discussing the underlying subtleties. As an illustration, we study a particular two-qubit universe model, obtaining the exact master equations for both parties and calculating their effective Hamiltonians and internal energies as given by the recently devised minimal dissipation approach. In this case, we show that internal energies are neither additive nor conservative, which leads to unphysical features.

Scientific ReportsVol. 15(1)
Universidade Federal de São Carlos (BR), Universidade de São Paulo (BR), Technology Innovation Institute (AE)
Fundação de Amparo à Pesquisa do Estado de São Paulo, Conselho Nacional de Desenvolvimento Científico e Tecnológico, Instituto Nacional de Ciência e Tecnologia de Informação Quântica
Openalex Percentile: Top 9%
Advanced Thermodynamics and Statistical Mechanics
2.65
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