<p>MoS<sub>2</sub>-Doped Polyvinyl Alcohol Nanofiber Films Via Electrospinning for High-Performance Triboelectric Nanogenerators</p><p><br/></p>

<p>Electrospinning enables the fabrication of nanofiber films with large active surface area, high porosity, and controllable filler orientation, offering distinct advantages for fabricating high-performance triboelectric nanogenerators (TENGs). Here, we develop MoS<sub>2</sub>-doped electrospun polyvinyl alcohol (PVA) films for TENG fabrication and reveal the underlying mechanisms of their enhanced triboelectric performance. Compared with spin-coated films, electrospun films intrinsically deliver higher output due to their fibrous morphology, while incorporation of MoS<sub>2</sub> nanosheets further improves the performance. TENG with the optimized 2 wt.% MoS<sub>2</sub>-PVA electrospun film reached 994.0 V, 111.0 mA·m<sup>-2</sup>, and 136.3 μC·m<sup>-2</sup>, corresponding to 3.8, 3.8, and 3.0 folds enhancements over the spin-coated pristine PVA TENG. Mechanistic studies by experiments and theoretical analysis showed that this remarkable enhancement arises from the combined effects of morphology driven enlargement of effective contact area, MoS<sub>2</sub> induced surface charge modulation, and nanosheet alignment induced piezoelectric polarization. Detailed material characterizations, COMSOL simulations, and molecular dynamic calculations provide quantitative and atomistic insights into these contributions. These results establish a coherent structure-property-performance relationship and provide design rules for durable, biocompatible, and high output TENGs, highlighting their promise for wearable energy harvesting and self-powered sensing applications.</p>