Rapid stress release through thiol–thioester exchange in phenylic crosslinked polymers
This study presents a method to mitigate distortion of crosslinked films through photochemical crosslinking and catalytic thiol–thioester exchange. Bond rearrangement is catalysed by base liberated on photolysis of a photobase.
Authors
- Andrew K. Whittaker (ORCID: https://orcid.org/0000-0002-1948-8355)
- Idriss Blakey (ORCID: https://orcid.org/0000-0003-2389-6156)
- Charlotte Cutler
- Josua Markus (ORCID: https://orcid.org/0000-0001-6567-1241)
- Pratheep K. Annamalai (ORCID: https://orcid.org/0000-0002-7284-0813)
- Hui Peng (ORCID: https://orcid.org/0000-0002-9221-385X)
- Md. Daloar Hossain
Institutions
- Australian Research Council (AU)
- The University of Queensland (AU)
- University of Southern Queensland (AU)
- University at Albany, State University of New York (US)
- National Imaging Facility (AU)
Publication Details
- Journal
- Journal of Materials Chemistry C
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5tc02110c
- Primary Topic
- Advanced Polymer Synthesis and Characterization
- Type
- article
- Field-Weighted Citation Impact
- 0.00