Cobalt- and ionic liquid-functionalized covalent organic framework for cooperative catalytic CO <sub>2</sub> cycloaddition
A nanofibrous crystalline cobalt(II)-anchored, imine-linked ionic covalent organic framework (Co-Py-COF) with a two-dimensional AA stacking structure was synthesized. This material exhibits outstanding catalytic activity for the cycloaddition of CO<sub>2</sub> under mild reaction conditions (1 atm, cocatalyst-free), attributed to the synergistic interaction between Co(II) ions and pyridinium groups.
Authors
- Bing‐Jian Yao (ORCID: https://orcid.org/0000-0002-8165-5871)
- Fei Li (ORCID: https://orcid.org/0000-0001-9822-7526)
- Jian Wang (ORCID: https://orcid.org/0000-0002-3298-6367)
- Xiao-kun Zhang (ORCID: https://orcid.org/0000-0002-8359-5008)
- Yu‐Bin Dong (ORCID: https://orcid.org/0000-0002-9698-8863)
Institutions
- Shandong Normal University (CN)
- Ministry of Education (ME)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04684j
- Citations
- 1
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.70