A bridging thiocarbyne ligand in diiron( <scp>i</scp> ) complexes enables unconventional isomerization pathways and structural diversity leading to potent cytotoxicity
Diiron bis-cyclopentadienyl complexes of type [Fe 2 Cp 2 (L′)(L)(μ-CO)(μ-CSMe)] + can be designed by appropriate choice of the monodentate ligands (L, L′) to tune aqueous solubility, lipophilicity, isomerization processes and cancer cell cytotoxicity.
Authors
- Gianluca Ciancaleoni (ORCID: https://orcid.org/0000-0001-5113-2351)
- Stefano Zacchini (ORCID: https://orcid.org/0000-0003-0739-0518)
- Sanja Mijatović (ORCID: https://orcid.org/0000-0001-9509-9098)
- Guido Pampaloni (ORCID: https://orcid.org/0000-0002-6375-4411)
- Ekatarina Mihajlović
- Fabio Marchetti (ORCID: https://orcid.org/0000-0002-3683-8708)
- Marija Mojić (ORCID: https://orcid.org/0000-0002-4906-9880)
- Biljana Dojčinović (ORCID: https://orcid.org/0000-0003-1479-8060)
- Sanja Jelača (ORCID: https://orcid.org/0000-0002-9848-6859)
- Lorenzo Biancalana (ORCID: https://orcid.org/0000-0002-9276-0095)
- Danijela Maksimović‐Ivanić (ORCID: https://orcid.org/0000-0002-8006-5079)
Institutions
- University of Pisa (IT)
- University of Belgrade (RS)
- Institute of Physics Belgrade (RS)
- University of Bologna (IT)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi01498k
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00