Honeycomb germanene flakes on Ag nano-islands

Since germanene cannot be exfoliated from a bulk material, and since Ge-based surface alloys are more stable than pure Ge monolayers (MLs) on metal surfaces, the synthesis of germanene flakes remains challenging. Here we report on the synthesis of germanene nanoflakes on Ag ML islands grown on Ag(111). The maximum achievable size is of the order of 30 nm, and germanene growth occurs due to the heavily oversaturated chemical potential for the Ge atoms confined on top of the Ag islands during growth. The nucleation of three-dimensional clusters, however, prevents the formation of larger germanene flakes.

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Publication Details

Journal
Journal of Physics Condensed Matter
Published
2025-09-25
DOI
https://doi.org/10.1088/1361-648x/ae0bdd
Primary Topic
Surface and Thin Film Phenomena
Type
article
Field-Weighted Citation Impact
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article

Honeycomb germanene flakes on Ag nano-islands

Hervé Cruguel, Marie-Christine Hanf, Romain Bernard, Geoffroy Prévot et al.
Journal of Physics Condensed Matter
Surface and Thin Film Phenomena
article

Honeycomb germanene flakes on Ag nano-islands

Hervé Cruguel, Marie-Christine Hanf, Romain Bernard, Geoffroy Prévot, Régis Stephan, Philippe Sonnet, Y. Borensztein, Kai Zhang
article en

Abstract

Since germanene cannot be exfoliated from a bulk material, and since Ge-based surface alloys are more stable than pure Ge monolayers (MLs) on metal surfaces, the synthesis of germanene flakes remains challenging. Here we report on the synthesis of germanene nanoflakes on Ag ML islands grown on Ag(111). The maximum achievable size is of the order of 30 nm, and germanene growth occurs due to the heavily oversaturated chemical potential for the Ge atoms confined on top of the Ag islands during growth. The nucleation of three-dimensional clusters, however, prevents the formation of larger germanene flakes.

Journal of Physics Condensed MatterVol. 37(41)
Centre National de la Recherche Scientifique (FR), Université de Haute-Alsace (FR), Sorbonne Université (FR), Institut de Sciences des Matériaux de Mulhouse (FR), Institut des NanoSciences de Paris (FR), Université de Strasbourg (FR)
Openalex Percentile: Top 79%
Surface and Thin Film Phenomena
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