Photochemical Borylation of Nitroarenes

We describe a straightforward light-driven strategy for transforming nitroarenes to aryl boronic esters. This transformation proceeds under mild conditions at ambient temperature and tolerates a wide variety of functional groups. The approach offers an operationally simple and practical alternative for preparing aryl boronic esters directly from nitroarenes, which are readily available and inexpensive starting materials.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2025-09-25
DOI
https://doi.org/10.1021/acs.joc.5c01636
Primary Topic
Advanced Photocatalysis Techniques
Type
article
Field-Weighted Citation Impact
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article

Photochemical Borylation of Nitroarenes

Shuai Tang, Feng Kong, Jingrong Cao, Hua Zhang et al.
The Journal of Organic Chemistry
Advanced Photocatalysis Techniques
article

Photochemical Borylation of Nitroarenes

Shuai Tang, Feng Kong, Jingrong Cao, Hua Zhang, Xiaoyun Hu, Linghe Li
article en

Abstract

We describe a straightforward light-driven strategy for transforming nitroarenes to aryl boronic esters. This transformation proceeds under mild conditions at ambient temperature and tolerates a wide variety of functional groups. The approach offers an operationally simple and practical alternative for preparing aryl boronic esters directly from nitroarenes, which are readily available and inexpensive starting materials.

The Journal of Organic ChemistryVol. 90(40)
Minzu University of China (CN)
Openalex Percentile: Top 82%
Advanced Photocatalysis Techniques
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