Study of the Magnetohydrodynamic Instability and a New Suppression Method in Liquid Metal Batteries

As a strong candidate for energy storage applications, Liquid Metal Batteries (LMBs) have the advantages of higher current density, longer cycle life, and simpler manufacturing of large-scale storage systems. Owing to the all-liquid construction, various kinds of Magnetohydrodynamic instabilities (MHDIs) are present in LMBs. In this paper, an in-depth study of the evolution process of MHDIs within LMBs has been conducted. By analyzing the characteristic velocity, the growth rate of instabilities γ has been defined so that the critical Hartmann number at which the instability occurs can be ascertained. A new critical parameter, mixed Reynolds number Remix, has been introduced to determine the duration of stable battery operation across varying charging/discharging currents, including those that may surpass the prescribed safe limits. Finally, a method for mitigating magnetohydrodynamic instability in LMBs through the configuration of busbar current is proposed, which can be seamlessly integrated with parallel battery packs. A comparative analysis of LMBs operation with/without bus current configuration reveals that when bus current is appropriately configured, the magnetic field strength within the battery undergoes a notable reduction of 40%, leading to a significant suppression of instability. The conclusions offer theoretical underpinnings for the application of LMBs in large-scale grid-level energy storage systems.

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Publication Details

Journal
Magnetochemistry
Published
2025-09-25
DOI
https://doi.org/10.3390/magnetochemistry11100084
Primary Topic
Molten salt chemistry and electrochemical processes
Type
article
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article

Study of the Magnetohydrodynamic Instability and a New Suppression Method in Liquid Metal Batteries

Ben‐Wen Li, Qiguang Li, J. H. Song, Baozhi Chen et al.
Magnetochemistry
Molten salt chemistry and electrochemical processes
article

Study of the Magnetohydrodynamic Instability and a New Suppression Method in Liquid Metal Batteries

Ben‐Wen Li, Qiguang Li, J. H. Song, Baozhi Chen, En-Qi Zhu, Xiaozhong Zuo
article en

Abstract

As a strong candidate for energy storage applications, Liquid Metal Batteries (LMBs) have the advantages of higher current density, longer cycle life, and simpler manufacturing of large-scale storage systems. Owing to the all-liquid construction, various kinds of Magnetohydrodynamic instabilities (MHDIs) are present in LMBs. In this paper, an in-depth study of the evolution process of MHDIs within LMBs has been conducted. By analyzing the characteristic velocity, the growth rate of instabilities γ has been defined so that the critical Hartmann number at which the instability occurs can be ascertained. A new critical parameter, mixed Reynolds number Remix, has been introduced to determine the duration of stable battery operation across varying charging/discharging currents, including those that may surpass the prescribed safe limits. Finally, a method for mitigating magnetohydrodynamic instability in LMBs through the configuration of busbar current is proposed, which can be seamlessly integrated with parallel battery packs. A comparative analysis of LMBs operation with/without bus current configuration reveals that when bus current is appropriately configured, the magnetic field strength within the battery undergoes a notable reduction of 40%, leading to a significant suppression of instability. The conclusions offer theoretical underpinnings for the application of LMBs in large-scale grid-level energy storage systems.

MagnetochemistryVol. 11(10)
Dalian University of Technology (CN)
Openalex Percentile: Top 77%
Molten salt chemistry and electrochemical processes
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