1H NMR-based small molecular metabolites characterization and free fatty acid composition of Xuanwei ham and Jinhua ham

Xuanwei ham (XW) and Jinhua ham (JH), two representative Chinese dry-cured hams, exhibit distinct flavor profiles. This study combined <sup>1</sup>H NMR metabolomics and GC-MS to compare their free fatty acid (FFA) compositions and small-molecule metabolites. XW showed higher retention of polyunsaturated fatty acids (PUFAs) and significantly more linoleic acid in subcutaneous fat (+39.29 %, <i>p</i> < 0.05), along with greater oxidative stability. In contrast, JH displayed severe lipid oxidation under high-temperature fermentation, as indicated by a sharp drop in intramuscular PUFA/SFA ratio. NMR revealed higher levels of umami-enhancing metabolites (taurine, glutamate, lysine) in XW. Multivariate analysis confirmed significant metabolic divergence between the hams, highlighting how raw materials and processing conditions shape their unique flavors.

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Publication Details

Journal
Food Chemistry X
Published
2025-09-24
DOI
https://doi.org/10.1016/j.fochx.2025.103071
Primary Topic
Meat and Animal Product Quality
Type
article
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article

1H NMR-based small molecular metabolites characterization and free fatty acid composition of Xuanwei ham and Jinhua ham

Jia Liu, Ling Li, Nannan Zhou, Wen Xun et al.
Food Chemistry X
Meat and Animal Product Quality
article

1H NMR-based small molecular metabolites characterization and free fatty acid composition of Xuanwei ham and Jinhua ham

Jia Liu, Ling Li, Nannan Zhou, Wen Xun, Guozhou Liao, Jin Tan, Yanfei Du, Guiying Wang, Shuai Tang, Ruwei Ren
article en

Abstract

Xuanwei ham (XW) and Jinhua ham (JH), two representative Chinese dry-cured hams, exhibit distinct flavor profiles. This study combined <sup>1</sup>H NMR metabolomics and GC-MS to compare their free fatty acid (FFA) compositions and small-molecule metabolites. XW showed higher retention of polyunsaturated fatty acids (PUFAs) and significantly more linoleic acid in subcutaneous fat (+39.29 %, <i>p</i> < 0.05), along with greater oxidative stability. In contrast, JH displayed severe lipid oxidation under high-temperature fermentation, as indicated by a sharp drop in intramuscular PUFA/SFA ratio. NMR revealed higher levels of umami-enhancing metabolites (taurine, glutamate, lysine) in XW. Multivariate analysis confirmed significant metabolic divergence between the hams, highlighting how raw materials and processing conditions shape their unique flavors.

Food Chemistry XVol. 31
Yunnan Agricultural University (CN)
Openalex Percentile: Top 70%
Meat and Animal Product Quality
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