Efficient Goodness‐of‐Fit Tests for the Maxwell–Boltzmann Distribution via Stein‐Type Characterization With Applications to (Un)censored Data

ABSTRACT Understanding molecular motion in an ideal gas is fundamental to thermodynamics, yet directly measuring individual molecular velocities remains impractical. The Maxwell–Boltzmann (MB) distribution provides a well‐established statistical model for describing the distribution of molecular speeds. In this study, we propose efficient goodness‐of‐fit tests for the MB distribution with unknown parameters, leveraging a novel fixed‐point characterization derived from a Stein‐type identity. We derive the asymptotic distribution of the proposed test statistic and establish its consistency against a broad class of alternative distributions. Furthermore, we extend the methodology to handle right‐censored data, broadening its applicability to real‐world scenarios where incomplete observations are common. The performance of our approach is evaluated through extensive Monte Carlo simulations, and its practical utility is demonstrated with applications to empirical data.

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Journal
Stat
Published
2025-09-24
DOI
https://doi.org/10.1002/sta4.70097
Primary Topic
Statistical Distribution Estimation and Applications
Type
article
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article

Efficient Goodness‐of‐Fit Tests for the Maxwell–Boltzmann Distribution via Stein‐Type Characterization With Applications to (Un)censored Data

Bruno Ebner, Ganesh Vishnu Avhad
Stat
Statistical Distribution Estimation and Applications
article

Efficient Goodness‐of‐Fit Tests for the Maxwell–Boltzmann Distribution via Stein‐Type Characterization With Applications to (Un)censored Data

Bruno Ebner, Ganesh Vishnu Avhad
article en

Abstract

ABSTRACT Understanding molecular motion in an ideal gas is fundamental to thermodynamics, yet directly measuring individual molecular velocities remains impractical. The Maxwell–Boltzmann (MB) distribution provides a well‐established statistical model for describing the distribution of molecular speeds. In this study, we propose efficient goodness‐of‐fit tests for the MB distribution with unknown parameters, leveraging a novel fixed‐point characterization derived from a Stein‐type identity. We derive the asymptotic distribution of the proposed test statistic and establish its consistency against a broad class of alternative distributions. Furthermore, we extend the methodology to handle right‐censored data, broadening its applicability to real‐world scenarios where incomplete observations are common. The performance of our approach is evaluated through extensive Monte Carlo simulations, and its practical utility is demonstrated with applications to empirical data.

StatVol. 14(4)
Karlsruhe Institute of Technology (DE), Indian Institute of Technology Tirupati (IN)
Openalex Percentile: Top 75%
Statistical Distribution Estimation and Applications
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