Rh-catalyzed [3 + 2] cyclization of (hetero)cyclic 1,3-dicarbonyls with 2-aminoarylboronic esters to access carbazolones
The first Suzuki-type [3 + 2] cyclization of cyclic 1,3-dicarbonyls with 2-aminoarylboronic esters has been developed. With eco-friendly EtOH/H 2 O as solvent, a series of structurally and electronically diverse carbazolones can be readily obtained.
Authors
- Zhonghua Gu (ORCID: https://orcid.org/0000-0003-2811-538X)
- Feng Qiu (ORCID: https://orcid.org/0000-0001-5505-8670)
- Hui Xiong (ORCID: https://orcid.org/0000-0003-4138-2992)
- Bei Wan
- Shaoyu Mai (ORCID: https://orcid.org/0000-0002-9318-7606)
- Yi Deng (ORCID: https://orcid.org/0000-0003-0313-7830)
- Ce Liu (ORCID: https://orcid.org/0009-0007-2093-4934)
- Qingfeng Du (ORCID: https://orcid.org/0000-0002-7599-7306)
Institutions
- Guangzhou University of Chinese Medicine (CN)
- Third Affiliated Hospital of Southern Medical University (CN)
- TCM-Intigrated Cancer Center of Southern Medical University (CN)
- Southern Medical University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo01079a
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00