Double Complex Salt [Co(NH3)6][Fe(CN)6] Plasma Treatment

The method of obtaining functional materials almost always influences the physicochemical properties of the resulting substances. The plasma treatment of solid materials is considered to be a more energy efficient method when compared with thermal destruction. Our work is the first to treat double complex salt (DCS) [Co(NH3)6][Fe(CN)6] with different plasma discharge modes. We have demonstrated the possibility of obtaining a single-phase spinel with a CoFe2O4 structure as a result of the calcination in air of the plasma destruction product. The crystallite sizes of the obtained spinel are 40 nm, with a lattice constant 8.38 Å.

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Publication Details

Journal
Thermo
Published
2025-09-22
DOI
https://doi.org/10.3390/thermo5030036
Citations
1
Primary Topic
Magnetism in coordination complexes
Type
article
Field-Weighted Citation Impact
0.43
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Double Complex Salt [Co(NH3)6][Fe(CN)6] Plasma Treatment

Diana Manukovskaya, A. A. Grabchak, М. В. Куликова, O. V. Golubev et al.
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Magnetism in coordination complexes
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article

Double Complex Salt [Co(NH3)6][Fe(CN)6] Plasma Treatment

Diana Manukovskaya, A. A. Grabchak, М. В. Куликова, O. V. Golubev, M. I. Ivantsov, V. Yu. Vinogradov, S. A. Svidersky, Alevtina N. Gosteva
article en
1 citations

Abstract

The method of obtaining functional materials almost always influences the physicochemical properties of the resulting substances. The plasma treatment of solid materials is considered to be a more energy efficient method when compared with thermal destruction. Our work is the first to treat double complex salt (DCS) [Co(NH3)6][Fe(CN)6] with different plasma discharge modes. We have demonstrated the possibility of obtaining a single-phase spinel with a CoFe2O4 structure as a result of the calcination in air of the plasma destruction product. The crystallite sizes of the obtained spinel are 40 nm, with a lattice constant 8.38 Å.

ThermoVol. 5(3)
A.V. Topchiev Institute of Petrochemical Synthesis (RU), Kola Science Centre (RU)
Openalex Percentile: Top 36%
Magnetism in coordination complexes
0.43
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