Photoinduced Copper‐Catalyzed Radical Ring‐Opening Azidation of Cyclic Oxime Esters
A photoinduced copper‐catalyzed radical ring‐opening azidation of cyclic oxime esters has been developed for the synthesis of valuable γ ‐azido alkylnitriles. Furthermore, a one‐pot sequential strategy integrating this ring‐opening azidation with copper‐catalyzed azide–alkyne cycloaddition is successfully implemented, enabling the direct construction of 1,2,3‐triazole derivatives in a single operation.
Authors
- Tao Zou (ORCID: https://orcid.org/0000-0002-6510-5749)
- Libo Yang (ORCID: https://orcid.org/0000-0002-4732-0023)
- Xiaoshuang Zhou (ORCID: https://orcid.org/0000-0001-6610-6834)
- Jing Li (ORCID: https://orcid.org/0000-0001-7792-4322)
- Ya‐Min Li (ORCID: https://orcid.org/0000-0003-4233-5274)
- Yuan Qu (ORCID: https://orcid.org/0000-0001-8423-3976)
- Jia Hu (ORCID: https://orcid.org/0000-0002-0686-5270)
Institutions
- Kunming University of Science and Technology (CN)
- Fuyang Normal University (CN)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2025-09-22
- DOI
- https://doi.org/10.1002/adsc.70133
- Primary Topic
- Click Chemistry and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00