Long-range molecular energy transfer mediated by strong coupling to plasmonic topological edge states

Strong coupling between light and molecular matter is currently attracting interest both in chemistry and physics, in the fast-growing field of molecular polaritonics [1] . The large near-field enhancement of the electric field of plasmonic surfaces and their high tunability make arrays of metallic nanoparticles an interesting platform to achieve and control strong coupling. Two dimensional plasmonic arrays with several nanoparticles per unit cell and crystalline symmetries can host topological edge and corner states. Here we explore the coupling of molecular materials to these edge states using a coupled-dipole framework including long-range interactions. We study both weak and strong coupling regimes and demonstrate that coupling to topological edge states can be employed to enhance highly-directional long-range energy transfer between molecules [2].

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Publication Details

Journal
EPJ Web of Conferences
Published
2025-01-01
DOI
https://doi.org/10.1051/epjconf/202533509003
Primary Topic
Molecular Junctions and Nanostructures
Type
article
Field-Weighted Citation Impact
0.00

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article

Long-range molecular energy transfer mediated by strong coupling to plasmonic topological edge states

Marie S. Rider, Vincenzo Giannini, William L. Barnes, José A. Sánchez‐Gil et al.
EPJ Web of Conferences
Molecular Junctions and Nanostructures
article

Long-range molecular energy transfer mediated by strong coupling to plasmonic topological edge states

Marie S. Rider, Vincenzo Giannini, William L. Barnes, José A. Sánchez‐Gil, Álvaro Buendía
article en

Abstract

Strong coupling between light and molecular matter is currently attracting interest both in chemistry and physics, in the fast-growing field of molecular polaritonics [1] . The large near-field enhancement of the electric field of plasmonic surfaces and their high tunability make arrays of metallic nanoparticles an interesting platform to achieve and control strong coupling. Two dimensional plasmonic arrays with several nanoparticles per unit cell and crystalline symmetries can host topological edge and corner states. Here we explore the coupling of molecular materials to these edge states using a coupled-dipole framework including long-range interactions. We study both weak and strong coupling regimes and demonstrate that coupling to topological edge states can be employed to enhance highly-directional long-range energy transfer between molecules [2].

EPJ Web of ConferencesVol. 335
University of Exeter (GB), Technology Innovation Institute (AE), International Iberian Nanotechnology Laboratory (PT), Instituto de Estructura de la Materia (ES), University of Bath (GB)
Ministerio de Ciencia, Innovación y Universidades, European Commission, Fundacja na rzecz Nauki Polskiej, European Regional Development Fund, Agencia Estatal de Investigación
Openalex Percentile: Top 75%
Molecular Junctions and Nanostructures
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