Research on the Effect of Argon–Nitrogen Ratio on the Mechanical Properties and Corrosion Behavior of CrN-Ag Self-Lubricating Coatings

Self-lubricating coatings are an effective solution for achieving stable and reliable lubrication in mechanical equipment; however, most self-lubricating coatings currently available still have certain shortcomings in terms of lubricity. In this paper, by regulating the argon and nitrogen flow ratio, a CrN-Ag composite self-lubricating coating with excellent lubrication performance was prepared, with a minimum wear rate and friction coefficient of only 2.3 mm3·10−5/N·m and 0.15, respectively, and a stable performance during long-term service. Furthermore, through systematic characterization of the coating composition, structure, and performance, the laws of the coating’s evolution were revealed based on the argon–nitrogen ratio. The results confirmed that the argon-to-nitrogen ratio had no significant effect on the coating composition and structure, while the addition of Ag dominated the high-temperature oxidation process of the coating and improved its tribological properties. In addition, while increasing the nitrogen flow ratio to a certain extent is beneficial for preparing coatings with high bonding strength and low wear rates and friction coefficients, at the same time, an excessively high nitrogen flow ratio can reduce the density of the coating, increase its hydrophilicity, and deteriorate its corrosion resistance.