Hydrate Formation and Mitigation Methods Under Multiple Operational Conditions in Deepwater Drilling

During deepwater drilling operations, when influx gas invades the wellbore, gas hydrates may form through the combination of the gas with free water in the drilling fluid under favorable temperature and pressure conditions. This process can alter the physical properties and flow behavior of the wellbore fluid, potentially leading to safety incidents. To prevent natural gas hydrate formation, mitigate wellbore blockages caused by hydrates, and address the associated safety hazards, this study conducted laboratory experiments to investigate hydrate formation and remediation under multiple deepwater drilling conditions. The hydrate formation boundaries for four different drilling fluid systems—seawater-based bentonite mud, seawater polymer mud, Plus/KCl mud, and HEM mud—were determined for varying well depths and pressure–temperature conditions, and corresponding trend lines were fitted. Key results reveal that a higher carbon content promotes hydrate formation, and the phase equilibrium curves also reveal significant differences among the four drilling fluids. The hydrate aggregation states and blockage processes were clarified for three typical drilling scenarios: drilling, well killing, and drilling suspension. Hydrate formation risk is negligible during normal circulation but increases dramatically during well-killing operations, significantly shrinking the safe operational window. A comparative analysis identified that adding 1% P(M-VCL), a kinetic hydrate inhibitor, to the drilling fluid was the most effective solution, demonstrating superior performance in delaying hydrate nucleation and preventing agglomeration. The study established a complete formation–inhibition–remediation approach for hydrate management in deepwater drilling, thereby enhancing operational safety and efficiency.

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Publication Details

Journal
Processes
Published
2025-09-21
DOI
https://doi.org/10.3390/pr13093008
Citations
1
Primary Topic
Methane Hydrates and Related Phenomena
Type
article
Field-Weighted Citation Impact
0.86
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article

Hydrate Formation and Mitigation Methods Under Multiple Operational Conditions in Deepwater Drilling

Shujie Liu, Ying Zhao, Yanjun Li, Lei Li et al.
1 citations
Processes
Methane Hydrates and Related Phenomena
0.86
article

Hydrate Formation and Mitigation Methods Under Multiple Operational Conditions in Deepwater Drilling

Shujie Liu, Ying Zhao, Yanjun Li, Lei Li, Shuzhan Li, Deli Gao
article en
1 citations

Abstract

During deepwater drilling operations, when influx gas invades the wellbore, gas hydrates may form through the combination of the gas with free water in the drilling fluid under favorable temperature and pressure conditions. This process can alter the physical properties and flow behavior of the wellbore fluid, potentially leading to safety incidents. To prevent natural gas hydrate formation, mitigate wellbore blockages caused by hydrates, and address the associated safety hazards, this study conducted laboratory experiments to investigate hydrate formation and remediation under multiple deepwater drilling conditions. The hydrate formation boundaries for four different drilling fluid systems—seawater-based bentonite mud, seawater polymer mud, Plus/KCl mud, and HEM mud—were determined for varying well depths and pressure–temperature conditions, and corresponding trend lines were fitted. Key results reveal that a higher carbon content promotes hydrate formation, and the phase equilibrium curves also reveal significant differences among the four drilling fluids. The hydrate aggregation states and blockage processes were clarified for three typical drilling scenarios: drilling, well killing, and drilling suspension. Hydrate formation risk is negligible during normal circulation but increases dramatically during well-killing operations, significantly shrinking the safe operational window. A comparative analysis identified that adding 1% P(M-VCL), a kinetic hydrate inhibitor, to the drilling fluid was the most effective solution, demonstrating superior performance in delaying hydrate nucleation and preventing agglomeration. The study established a complete formation–inhibition–remediation approach for hydrate management in deepwater drilling, thereby enhancing operational safety and efficiency.

ProcessesVol. 13(9)
China National Offshore Oil Corporation (China) (CN), China University of Petroleum, Beijing (CN), Hainan University (CN), Oil and Gas Center (CN)
Openalex Percentile: Top 23%
Methane Hydrates and Related Phenomena
0.86
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