Catalyst Design and Mechanistic Insights for Non‐Thermal Plasma Ammonia Synthesis

Hydrogen storage technology based on ammonia carriers is a key part of the transition from fossil fuels to low-carbon energy sources. However, the high energy consumption and high carbon path dependency of the traditional ammonia industry are the core challenges constraining the development of current technologies. In this review, we focus on the core advantages of low-temperature plasma chemistry in ammonia synthesis, including mild conditions, environmental friendliness, flexibility, and controllability. We then propose a powerful approach for transitioning traditional ammonia synthesis technology in a sustainable direction. Firstly, we systematically sort out the time evolution of the plasma ammonia synthesis reactor and elucidate the mode of action of plasma-assisted ammonia synthesis. In particular, we provide an in-depth analysis of design optimization strategies for plasma catalysts to explore key catalytic mechanisms in ammonia synthesis systems. Finally, we evaluate the performance index of the existing plasma ammonia synthesis system and suggest feasible directions for future research to further improve the energy efficiency of the technology, promoting the development of the ammonia production process in a more sustainable and advanced direction.