Preparation and Characterization of Ionic Liquid Supported on Fe3O4-Lignin and Investigation of Its Catalytic Activity in the Synthesis of Dihydropyrano[3,2-c] chromene Derivatives

To extend the use of supported ionic liquids as effective heterogeneous catalysts, in this research, the ionic liquid immobilized on magnetic lignin (Fe3O4-lignin-SO3/IL) was used as an environmentally friendly, and recyclable catalyst for the synthesis of dihydropyrano[3,2-c]chromene derivatives via a one-pot reaction between aromatic aldehydes, malononitrile, and 4-hydroxycoumarin. This method offers the benefits of high yield, short reaction times, straightforward processing, and its potential for green applications in pharmaceutical and chemical sectors. Furthermore, the detailed role of Fe3O4-lignin-SO3/IL as a catalyst in chemical reactions was examined, providing insights into its mechanism and potential uses in organic synthesis and other chemical processes.

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Publication Details

Journal
Acta chimica slovenica
Published
2025-09-18
DOI
https://doi.org/10.17344/acsi.2025.9250
Primary Topic
Multicomponent Synthesis of Heterocycles
Type
article
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article

Preparation and Characterization of Ionic Liquid Supported on Fe3O4-Lignin and Investigation of Its Catalytic Activity in the Synthesis of Dihydropyrano[3,2-c] chromene Derivatives

Mahnaz Farahi, Majidreza Gerami
Acta chimica slovenica
Multicomponent Synthesis of Heterocycles
article

Preparation and Characterization of Ionic Liquid Supported on Fe3O4-Lignin and Investigation of Its Catalytic Activity in the Synthesis of Dihydropyrano[3,2-c] chromene Derivatives

Mahnaz Farahi, Majidreza Gerami
article en

Abstract

To extend the use of supported ionic liquids as effective heterogeneous catalysts, in this research, the ionic liquid immobilized on magnetic lignin (Fe3O4-lignin-SO3/IL) was used as an environmentally friendly, and recyclable catalyst for the synthesis of dihydropyrano[3,2-c]chromene derivatives via a one-pot reaction between aromatic aldehydes, malononitrile, and 4-hydroxycoumarin. This method offers the benefits of high yield, short reaction times, straightforward processing, and its potential for green applications in pharmaceutical and chemical sectors. Furthermore, the detailed role of Fe3O4-lignin-SO3/IL as a catalyst in chemical reactions was examined, providing insights into its mechanism and potential uses in organic synthesis and other chemical processes.

Acta chimica slovenicaVol. 72(3)
OSRAM (United States) (US), The Farah Hospital (JO)
Openalex Percentile: Top 81%
Multicomponent Synthesis of Heterocycles
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Preparation and Characterization of Ionic Liquid Supported on Fe3O4-Lignin and Investigation of Its Catalytic Activity in the Synthesis of Dihydropyrano[3,2-c] chromene Derivatives — Mahnaz Farahi, Majidreza Gerami · Acta chimica slovenica (2025) | TGRS Research Map | TGRS