Synthesis of Bis‐Arylated Squaryls via Addition of Organocopper Species onto Squaryl Dichlorides

Squaric chlorides serve as convenient, readily available building blocks in the synthetic path toward unsymmetrically substituted squaryls. The use of in situ generated arylcopper reagents enables precise, selective control over stoichiometry and facilitates the creation of a diverse library of sophisticated structures.

Authors

Flavie Rambaud
Sven Scholz (ORCID: https://orcid.org/0009-0000-5266-0455)
Erik Friedrich (ORCID: https://orcid.org/0000-0002-7175-2221)
Dorian Didier (ORCID: https://orcid.org/0000-0002-6358-1485)
Bilel Boutet (ORCID: https://orcid.org/0009-0009-5013-2953)
Markus Cedzich

Institutions

Darmstadt University of Applied Sciences (DE)
Technische Universität Darmstadt (DE)

Publication Details

Journal: European Journal of Organic Chemistry
Published: 2025-09-18
DOI: https://doi.org/10.1002/ejoc.202500623
Citations: 2
Primary Topic: Catalytic Cross-Coupling Reactions
Type: article
Field-Weighted Citation Impact: 1.87

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article

Synthesis of Bis‐Arylated Squaryls via Addition of Organocopper Species onto Squaryl Dichlorides

Flavie Rambaud, Sven Scholz, Erik Friedrich, Dorian Didier et al.

Sep 18, 2025

2 citations

European Journal of Organic Chemistry

Catalytic Cross-Coupling Reactions

1.87

article

Synthesis of Bis‐Arylated Squaryls via Addition of Organocopper Species onto Squaryl Dichlorides

Flavie Rambaud, Sven Scholz, Erik Friedrich, Dorian Didier, Bilel Boutet, Markus Cedzich

September 18, 2025article en

2 citations

Abstract

Squaric chlorides serve as convenient, readily available building blocks in the synthetic path toward unsymmetrically substituted squaryls. The use of in situ generated arylcopper reagents enables precise, selective control over stoichiometry and facilitates the creation of a diverse library of sophisticated structures.

European Journal of Organic ChemistryVol. 28(39)

Darmstadt University of Applied Sciences (DE), Technische Universität Darmstadt (DE)

Openalex Percentile: Top 13%

Catalytic Cross-Coupling Reactions

1.87

DOI Open Access PDF OpenAlex

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