New Corono Asymmetrical <i>N‐Bis</i> ‐Heterocyclic <i>Bis</i> ‐Imidazolium Macrocycle Salt, Preliminary Physicochemical Studies, X‐Ray Structures, and Biological Evaluation
ABSTRACT We describe here the preparation of a new class of photosensitizers cyclophane represented by a family of asymmetrical N ‐ bisheterocyclic bis ‐imidazolium bromide macrocycles. 1H NMR, 2D NMR, mass spectroscopy measurements, crystallographic x‐ray structures and photophysical properties of these cyclophane imidazolium salts are described, as well as the evaluation of their anti‐microbial activity.
Authors
- Arnaud Risler (ORCID: https://orcid.org/0000-0002-8227-1394)
- Bertrand Fournier (ORCID: https://orcid.org/0000-0001-7302-0182)
- Hannah Kunstek
- Florence Dumarçay‐Charbonnier (ORCID: https://orcid.org/0000-0002-7034-2482)
- Philippe Arnoux (ORCID: https://orcid.org/0000-0002-6834-9597)
- Hiba Hussein
- Stéphanie Philippot
- Mélaine Wang
- Mihayl Varbanov (ORCID: https://orcid.org/0000-0002-2515-3009)
- Tristan Hergot
- Céline Frochot
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Paris-Saclay (FR)
- Institut des Neurosciences Paris-Saclay (FR)
- Centre Hospitalier Régional et Universitaire de Nancy (FR)
- CentraleSupélec (FR)
- Université de Lorraine (FR)
Publication Details
- Journal
- Journal of Heterocyclic Chemistry
- Published
- 2025-09-18
- DOI
- https://doi.org/10.1002/jhet.70019
- Primary Topic
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00