Epitaxial Growth Control of Crystalline Morphology and Electronic Transport in InSb Nanowires: Competition Between Axial and Radial Growth Modes

This study investigates the morphological evolution of epitaxial indium antimonide (InSb) nanowires (NWs) grown via chemical vapor deposition (CVD). We systematically explored the influence of key growth parameters-temperature (300 °C to 480 °C), source material composition, gold (Au) nanoparticle catalyst size, and growth duration-on the resulting NW morphology, specifically focusing on NW length and tapering. Our findings reveal that the competition between axial and radial growth modes, which are governed by different growth mechanisms, dictates the final nanowire shape. An optimal growth condition was identified that yields straight and minimally tapered InSb NWs. High-resolution transmission electron microscopy (TEM) confirmed that these nanowires grow preferentially along the <110> direction, and electrical characterization via field-effect transistor (NW-FET) measurements showed that they are n-type semiconductors.