Charge-transfer modulated chiroptical azacyclooctatetraene-fused [5]helicenes with AIE features

Azacyclooctatetraene-fused [5]helicene scaffolds are integrated with phenazine to afford broadly tunable thermally activated delayed fluorescence emitters (peaks ranging from 555 to 843 nm). The new emitters exhibit circularly polarized luminescence with dissymmetry factors up to 1.5 × 10<sup>-2</sup>, and characteristic aggregation-induced emission.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04747a
Primary Topic
Synthesis and Properties of Aromatic Compounds
Type
article
Field-Weighted Citation Impact
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article

Charge-transfer modulated chiroptical azacyclooctatetraene-fused [5]helicenes with AIE features

Xiaojun Yin, Yulan Li, Jikun Chen, Jiacheng Ma et al.
Chemical Communications
Synthesis and Properties of Aromatic Compounds
article

Charge-transfer modulated chiroptical azacyclooctatetraene-fused [5]helicenes with AIE features

Xiaojun Yin, Yulan Li, Jikun Chen, Jiacheng Ma, Nengquan Li, Chuluo Yang, Mengyu Huang, Xuefeng Chen, Xuechao Mo
article en

Abstract

Azacyclooctatetraene-fused [5]helicene scaffolds are integrated with phenazine to afford broadly tunable thermally activated delayed fluorescence emitters (peaks ranging from 555 to 843 nm). The new emitters exhibit circularly polarized luminescence with dissymmetry factors up to 1.5 × 10<sup>-2</sup>, and characteristic aggregation-induced emission.

Chemical CommunicationsVol. 61(84)
Shenzhen University (CN)
Openalex Percentile: Top 81%
Synthesis and Properties of Aromatic Compounds
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