Solvent-dependent C–H⋯F–C pseudo-hydrogen bonding in fluorinated azobenzene Schiff bases: studies on structural and atropisomerism features
A pseudo-hydrogen bonding of the type C–F⋯H–C is observed in fluorinated azo Schiff bases under the influence of benzene solvent. This interaction was supported by NMR spectroscopy, which exhibited characteristic J H,F couplings of 2.0–2.4 Hz.
Authors
- B. N. Mahto
- Raman K. Singh (ORCID: https://orcid.org/0000-0002-7114-5384)
- Gopal Kumar Mahato (ORCID: https://orcid.org/0000-0002-9681-4767)
- Samridhi Patel (ORCID: https://orcid.org/0009-0002-8843-7815)
- Arnab Patra (ORCID: https://orcid.org/0000-0002-9318-3963)
- Girish Chandra (ORCID: https://orcid.org/0000-0001-6622-1242)
- Ujala Rani
Institutions
- Jai Prakash University (IN)
- Central University of South Bihar (IN)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj02663f
- Primary Topic
- Axial and Atropisomeric Chirality Synthesis
- Type
- article
- Field-Weighted Citation Impact
- 0.00