Ultrasmall iridium nanoparticles on nitrogen-doped carbon cloth for efficient and durable acidic water splitting

Ultrasmall Ir nanoparticles on N-doped carbon cloth (Ir/N-CC) achieve record-low acidic HER (12 mV) and OER (210 mV) overpotentials and long-term stability of 2000 hours at 10 mA cm<sup>-2</sup>, surpassing Pt/C and IrO<sub>2</sub>. The electrolyzer (Ir/N-CC‖Ir/N-CC) operates at 1.49 V for 10 mA cm<sup>-2</sup>. The N-dopants enhance the kinetics <i>via</i> optimized *OH/*OOH adsorption.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc03954a
Primary Topic
Ammonia Synthesis and Nitrogen Reduction
Type
article
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article

Ultrasmall iridium nanoparticles on nitrogen-doped carbon cloth for efficient and durable acidic water splitting

Dong Cai, Huagui Nie, Zhi Yang, Jinjie Qian et al.
Chemical Communications
Ammonia Synthesis and Nitrogen Reduction
article

Ultrasmall iridium nanoparticles on nitrogen-doped carbon cloth for efficient and durable acidic water splitting

Dong Cai, Huagui Nie, Zhi Yang, Jinjie Qian, Yingying Xu, Xuemei Zhou, Yiru Wang
article en

Abstract

Ultrasmall Ir nanoparticles on N-doped carbon cloth (Ir/N-CC) achieve record-low acidic HER (12 mV) and OER (210 mV) overpotentials and long-term stability of 2000 hours at 10 mA cm<sup>-2</sup>, surpassing Pt/C and IrO<sub>2</sub>. The electrolyzer (Ir/N-CC‖Ir/N-CC) operates at 1.49 V for 10 mA cm<sup>-2</sup>. The N-dopants enhance the kinetics <i>via</i> optimized *OH/*OOH adsorption.

Chemical CommunicationsVol. 61(82)
Wenzhou University (CN)
Openalex Percentile: Top 86%
Ammonia Synthesis and Nitrogen Reduction
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