AgOTf-promoted transetherification of <i>p</i> -methoxybenzyl ethers with allyl and benzyl bromides

An AgOTf-promoted transetherification of p -methoxybenzyl ethers with allyl and benzyl bromides is reported. It features an unusual C–O/C–Br σ-bond metathesis via an oxonium intermediate, distinct from typical C–O/O–H or C–O/C–O σ-bond metathesis.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00945f
Primary Topic
Synthetic Organic Chemistry Methods
Type
article
Field-Weighted Citation Impact
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article

AgOTf-promoted transetherification of p -methoxybenzyl ethers with allyl and benzyl bromides

X.Q. Li, Yufan Yang, Wanshu Wang, Lu Gao et al.
Organic Chemistry Frontiers
Synthetic Organic Chemistry Methods
article

AgOTf-promoted transetherification of p -methoxybenzyl ethers with allyl and benzyl bromides

X.Q. Li, Yufan Yang, Wanshu Wang, Lu Gao, Dongyang Jiang, Zhenlei Song, Jimmy Wang
article en

Abstract

An AgOTf-promoted transetherification of p -methoxybenzyl ethers with allyl and benzyl bromides is reported. It features an unusual C–O/C–Br σ-bond metathesis via an oxonium intermediate, distinct from typical C–O/O–H or C–O/C–O σ-bond metathesis.

Organic Chemistry FrontiersVol. 12(24)
Sichuan University (CN)
Openalex Percentile: Top 81%
Synthetic Organic Chemistry Methods
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