Unveiling CF<sub>3</sub>SOCH<sub>3</sub>: synthesis, spectroscopic characterization, and conformational behavior of <i>S</i>-(trifluoromethyl)-<i>O</i>-(methyl) thioperoxide
The elusive S -(trifluoromethyl) O -(methyl) thioperoxide, CF 3 SOCH 3 , and its methyl deuterated isotopologue, CF 3 SOCD 3 were prepared for the first time via the reaction between CF 3 SCl and CH 3 OH or CD 3 OH, respectively.
Authors
- Mauricio F. Erben (ORCID: https://orcid.org/0000-0001-8467-2784)
- Helge Willner (ORCID: https://orcid.org/0009-0003-9766-0442)
- Sonia E. Ulic (ORCID: https://orcid.org/0000-0002-9179-9609)
- E. Espitia Cogollo (ORCID: https://orcid.org/0000-0002-4688-6631)
- Marlene Cuaquira Reina
- Carlos O. Della Védova (ORCID: https://orcid.org/0000-0002-2439-2147)
- Helmut Beckers (ORCID: https://orcid.org/0000-0002-7903-4291)
Institutions
- University of Wuppertal (DE)
- National University of Luján (AR)
- Universidad Nacional de La Plata (AR)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj03169a
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00