Synthesis and characterization of the first neutral hexacoordinated silole complexes
The first neutral hexacoordinated silole complexes were synthesized. Substituent patterns govern coordination modes and influence delocalization within diketonato ligands, markedly affecting photophysical properties and enabling charge-transfer excitations. This structural tunability provides a strategy to modulate the electronic and photophysical behavior of silole-based complexes, expanding their potential applications.
Authors
- Balázs Szathmári (ORCID: https://orcid.org/0000-0002-6122-2489)
- Attila Domján (ORCID: https://orcid.org/0000-0002-7432-6906)
- Ilona Kovács (ORCID: https://orcid.org/0000-0001-6929-8528)
- Balázs Volk (ORCID: https://orcid.org/0000-0002-2019-1874)
- Zsolt Kelemen (ORCID: https://orcid.org/0000-0002-4787-9804)
- Tamás Holczbauer (ORCID: https://orcid.org/0000-0003-2727-7037)
- Bence Balterer
Institutions
- Budapest University of Technology and Economics (HU)
- Egis Pharmaceuticals (Hungary) (HU)
- HUN-REN Research Centre for Natural Sciences (HU)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04234h
- Primary Topic
- Polyoxometalates: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00