[C(NH<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[C<sub>2</sub>H<sub>5</sub>(C<sub>2</sub>O<sub>4</sub>)]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs

Developing metal-free birefringent crystals is of great significance in laser technology. Herein, a metal-free birefringent crystal, [C(NH<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[C<sub>2</sub>H<sub>5</sub>(C<sub>2</sub>O<sub>4</sub>)]Cl, was rationally obtained <i>via</i> a hydrogen-bond-directed assembly of three distinct motifs. It exhibits a wide band gap (3.987 eV) and significant birefringence (0.120@546 nm), demonstrating the strategy's efficacy for metal-free UV birefringent materials.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04675k
Citations
2
Primary Topic
Fluorine in Organic Chemistry
Type
article
Field-Weighted Citation Impact
1.58
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article

[C(NH2)3]2[C2H5(C2O4)]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs

Zhi Fang, Yu-Ming Pan, Xinyou An
2 citations
Chemical Communications
Fluorine in Organic Chemistry
1.58
article

[C(NH2)3]2[C2H5(C2O4)]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs

Zhi Fang, Yu-Ming Pan, Xinyou An
article en
2 citations

Abstract

Developing metal-free birefringent crystals is of great significance in laser technology. Herein, a metal-free birefringent crystal, [C(NH<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[C<sub>2</sub>H<sub>5</sub>(C<sub>2</sub>O<sub>4</sub>)]Cl, was rationally obtained <i>via</i> a hydrogen-bond-directed assembly of three distinct motifs. It exhibits a wide band gap (3.987 eV) and significant birefringence (0.120@546 nm), demonstrating the strategy's efficacy for metal-free UV birefringent materials.

Chemical CommunicationsVol. 61(81)
China West Normal University (CN), Sichuan Normal University (CN)
Openalex Percentile: Top 15%
Fluorine in Organic Chemistry
1.58
DOISourceOpenAlex
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[C(NH<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[C<sub>2</sub>H<sub>5</sub>(C<sub>2</sub>O<sub>4</sub>)]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs — Zhi Fang, Yu-Ming Pan, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS