Crystal structure and Hirshfeld surface analysis of Cd(II) coordination polymer with adipic acid

The reaction of Cd(ClO4)2·2H2O salt with adipic acid (H2adi) and 4,4’-diaminodiphenylmethane (dadpm) in the mixture of DMF and CH3CN solvents, resulted in new Cd(II)-based 1D coordination polymer with the composition {[Cd(adi)(dmf)₂(H₂O)](H2O)2}n. The crystal structure was determined by X-ray single crystal diffraction, confirming a 1D polymer. IR spectroscopic analysis revealed the presence of functional groups, confirming the integration of the ligand into the compound. This study contributes to the development of complex materials with applications in materials chemistry and advanced technologies.

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Publication Details

Published
2025-01-01
DOI
https://doi.org/10.46727/c.v1.01-02-03-2025.p101-107
Primary Topic
Metal-Organic Frameworks: Synthesis and Applications
Type
article
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article

Crystal structure and Hirshfeld surface analysis of Cd(II) coordination polymer with adipic acid

Elena Melnic, Marina S. Fonarı, Nicoleta CRACIUN
Metal-Organic Frameworks: Synthesis and Applications
article

Crystal structure and Hirshfeld surface analysis of Cd(II) coordination polymer with adipic acid

Elena Melnic, Marina S. Fonarı, Nicoleta CRACIUN
article en

Abstract

The reaction of Cd(ClO4)2·2H2O salt with adipic acid (H2adi) and 4,4’-diaminodiphenylmethane (dadpm) in the mixture of DMF and CH3CN solvents, resulted in new Cd(II)-based 1D coordination polymer with the composition {[Cd(adi)(dmf)₂(H₂O)](H2O)2}n. The crystal structure was determined by X-ray single crystal diffraction, confirming a 1D polymer. IR spectroscopic analysis revealed the presence of functional groups, confirming the integration of the ligand into the compound. This study contributes to the development of complex materials with applications in materials chemistry and advanced technologies.

Openalex Percentile: Top 80%
Metal-Organic Frameworks: Synthesis and Applications
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