Effect of noncovalent interactions on the supramolecular architecture of Co(II) coordination compounds
The comparative study of isomeric Co(II) complexes based on 2,6-diacetylpyridine bis(isonicotinoylhydrazone) (H2L1) [Co(H2L1)(H2O)2]Cl2·3H2O (1) and 2,6-diacetylpyridine bis(nicotinoylhydrazone) (H2L2) [Co(H2L2)(H2O)2]Cl2·2.25H2O (2) has been realized. The chemical and structural composition of complexes 1 and 2 were established by the single crystal X-ray diffraction. The influence of hydrogen bonds and π···π interactions on supramolecular architecture were evaluated by Hirshfeld surface analysis followed by lattice energies calculations.
Authors
- Maria Cocu (ORCID: https://orcid.org/0000-0001-8572-0258)
- P. N. Bourosh (ORCID: https://orcid.org/0000-0002-3418-531X)
- Yurii Chumakov (ORCID: https://orcid.org/0000-0003-2582-2871)
- I. Bulhac (ORCID: https://orcid.org/0000-0002-2437-2875)
- Olga Danilescu (ORCID: https://orcid.org/0000-0001-9090-7164)
Publication Details
- Published
- 2025-01-01
- DOI
- https://doi.org/10.46727/c.v1.01-02-03-2025.p108-115
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00