Water uptake behaviour of semiconducting glasses formed from hybrid organic–inorganic perovskites

Here we present the uptake behaviour of mechanochemically synthesised crystalline HOIPs, of the form [TAlA][M(dca)<sub>3</sub>] (TAlA = tetraalkylammonium, M = Mn<sup>2+</sup> and Fe<sup>2+</sup>, dca = [C<sub>2</sub>N<sub>3</sub><sup>-</sup>] (dicyanamide)), and their melt-quenched glassy derivatives. The semiconducting nature of these materials, alongside their response to environmentally relevant stimuli, was explored using optoelectronic techniques alongside electrochemical analyses.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc02507a
Primary Topic
Glass properties and applications
Type
article
Field-Weighted Citation Impact
0.00

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article

Water uptake behaviour of semiconducting glasses formed from hybrid organic–inorganic perovskites

L. Charles Hardy, Isaiah Borne, Bethan Turner, Lauren McHugh et al.
Chemical Communications
Glass properties and applications
article

Water uptake behaviour of semiconducting glasses formed from hybrid organic–inorganic perovskites

L. Charles Hardy, Isaiah Borne, Bethan Turner, Lauren McHugh, Hongjun Niu, Jay McCarron, Olivia Dunlop, Sam D. Harding, Laura L J Whitfield
article en

Abstract

Here we present the uptake behaviour of mechanochemically synthesised crystalline HOIPs, of the form [TAlA][M(dca)<sub>3</sub>] (TAlA = tetraalkylammonium, M = Mn<sup>2+</sup> and Fe<sup>2+</sup>, dca = [C<sub>2</sub>N<sub>3</sub><sup>-</sup>] (dicyanamide)), and their melt-quenched glassy derivatives. The semiconducting nature of these materials, alongside their response to environmentally relevant stimuli, was explored using optoelectronic techniques alongside electrochemical analyses.

Chemical CommunicationsVol. 61(84)
University of Liverpool (GB)
European Commission, University of Liverpool, Engineering and Physical Sciences Research Council
Openalex Percentile: Top 79%
Glass properties and applications
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