Microwave-assisted Pd-catalyzed B–N cross-coupling for efficient functionalization of the carbaborate [CB <sub>11</sub> H <sub>12</sub> ] <sup>−</sup>
A highly efficient Pd-catalyzed B-N coupling of [12-I-CB<sub>11</sub>H<sub>11</sub>]<sup>-</sup> with amides and amines has been developed, enabling efficient access to nitrogen-functionalized carbaborate derivatives. The method proceeds under mild conditions with broad substrate scope, high yields, and minimal dehalogenation, offering a versatile platform for advanced material applications.
Authors
- Lianyu Chen (ORCID: https://orcid.org/0000-0003-3731-8592)
- Yujie Jin (ORCID: https://orcid.org/0000-0002-2444-4277)
- Jiyong Liu (ORCID: https://orcid.org/0000-0003-0444-957X)
- Simon Duttwyler (ORCID: https://orcid.org/0000-0001-9851-4920)
- Cheng Jiang (ORCID: https://orcid.org/0000-0002-5052-1037)
- Kang Zhang (ORCID: https://orcid.org/0000-0003-4166-4666)
Institutions
- Shaoxing University (CN)
- Zhejiang University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04753f
- Primary Topic
- Boron Compounds in Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00