Inkless rewritable paper enabled by a scalable photochromic membrane

Rewritable paper has attracted wide research attention in the field of environment-friendly information transmission owing to its potential to promote sustainable society development. Traditional organic dye-based rewritable paper may cause emission of pollution. To solve this problem, this study presents a flexible inorganic photochromic membrane by <i>in situ</i> growth of highly dispersed Cu-doped WO<sub>3</sub> nanoparticles in a polymethyl methacrylate matrix. Obvious discoloration of the as-prepared membrane can be repeated more than 200 times under alternating UV irradiation/heating based on an oxidation-reduction process between W<sup>6+</sup> and W<sup>5+</sup>. The proof of concept for rewritable paper and encryption algorithm is demonstrated herein. The results of this study are of great significance for the design and fabrication of a novel type of rewritable colorful paper.

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Publication Details

Journal
Dalton Transactions
Published
2025-01-01
DOI
https://doi.org/10.1039/d5dt01957e
Primary Topic
Electrowetting and Microfluidic Technologies
Type
article
Field-Weighted Citation Impact
0.00
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Inkless rewritable paper enabled by a scalable photochromic membrane

Pan Jia, Zhuoran Kuang, Zhong Yu, Rong-Wei Kou et al.
Dalton Transactions
Electrowetting and Microfluidic Technologies
article

Inkless rewritable paper enabled by a scalable photochromic membrane

Pan Jia, Zhuoran Kuang, Zhong Yu, Rong-Wei Kou, Xing Guo, Jingxia Wang, Tianyu Huang, Chenfang Zhang, Junchao Liu
article en

Abstract

Rewritable paper has attracted wide research attention in the field of environment-friendly information transmission owing to its potential to promote sustainable society development. Traditional organic dye-based rewritable paper may cause emission of pollution. To solve this problem, this study presents a flexible inorganic photochromic membrane by <i>in situ</i> growth of highly dispersed Cu-doped WO<sub>3</sub> nanoparticles in a polymethyl methacrylate matrix. Obvious discoloration of the as-prepared membrane can be repeated more than 200 times under alternating UV irradiation/heating based on an oxidation-reduction process between W<sup>6+</sup> and W<sup>5+</sup>. The proof of concept for rewritable paper and encryption algorithm is demonstrated herein. The results of this study are of great significance for the design and fabrication of a novel type of rewritable colorful paper.

Dalton TransactionsVol. 54(41)
Xi'an University of Technology (CN), Technical Institute of Physics and Chemistry (CN), University of Chinese Academy of Sciences (CN), Hebei Normal University (CN)
Openalex Percentile: Top 76%
Electrowetting and Microfluidic Technologies
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